The carboxylation of saturated hydrocarbons by Gif systems. (FeIII trispicolinate/P(OMe)3/CO/H2O2 in pyridine-acetic acid)

DOI: 10.1016/0040-4039(96)00102-5

Source and publish data:

Tetrahedron Letters p. 1555 - 1558 (1996)

Update date:2022-08-28

Topics:

Authors:

Barton, Derek H. R.

Beck, Albert H.

Delanghe, Nathalie C.

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Article abstract of DOI:10.1016/0040-4039(96)00102-5

Saturated hydrocarbons are transformed into the corresponding homologous carboxylic acids by treatment with Fe(Pa)₃/P(OMe)₃/CO/H₂O₂ in pyridine-acetic acid. Optimisation of the reaction conditions and mechanistics studies are reported.

Full text of DOI:10.1016/0040-4039(96)00102-5

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