Deprotection of Acetals and Silyl Ethers by DDQ. Is DDQ a Neutral Catalyst ?

DOI: 10.1246/cl.1993.165

Source and publish data:

Chemistry Letters p. 165 - 168 (1993)

Update date:2022-08-24

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Authors:

Oku, Akira

Kinugasa, Motoharu

Kamada, Tohru

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Article abstract of DOI:10.1246/cl.1993.165

2,3-Dichloro-5,6-dicyano-p-benzoquinone (DDQ) in wet ethyl acetate at room temperature catalytically hydrolyzed acyclic acetals effectively and selectively among ethereal functional groups such as dioxoranes, 1,3-dioxanes, oxiranes, TMS- and TBDMS ethers.The mechanism is discussed on the basis of the function of DDQ as a Lewis acid in a wet solvent. 1890

Full text of DOI:10.1246/cl.1993.165

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