Chemistry Letters p. 165 - 168 (1993)
Update date:2022-08-24
Topics:
Oku, Akira
Kinugasa, Motoharu
Kamada, Tohru
2,3-Dichloro-5,6-dicyano-p-benzoquinone (DDQ) in wet ethyl acetate at room temperature catalytically hydrolyzed acyclic acetals effectively and selectively among ethereal functional groups such as dioxoranes, 1,3-dioxanes, oxiranes, TMS- and TBDMS ethers.The mechanism is discussed on the basis of the function of DDQ as a Lewis acid in a wet solvent. 1890
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