Tetrahedron Letters p. 179 - 182 (1993)
Update date:2022-08-11
Topics:
Stary
Stara
Kocovsky
A new method has been developed which allows palladium(0)-catalyzed allylic substitution to occur between allylic alcohols and anionic C-nucleophiles: on reaction with Ph3B, the allylic alkoxide 7 is first converted in situ into the more reactive species 8 which then undergoes a Pd(0)-catalyzed reaction with lithiodiethyl malonate via the η3-complex 9.
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(1974)
