Journal of the Chemical Society. Chemical communications p. 141 - 142 (1980)
Update date:2022-08-16
Topics:
Hibbert, Frank
Robbins, Heather J.
The primary kinetic isotope effect (kH/kD) for proton transfer from protonated 1,8-bis(dimethylamino)-2,7-dimethoxynaphthalene to bases has a value of unity even for reactions for which the proton donor and acceptor have similar pK values, a condition which would have been expected to lead to a maximum isotope effect.
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