Existence and Reactivity of Bicyclic Annulenones. 2. Bicycloocta-1(5),3,7-triene-2,6-dione

DOI: 10.1021/jo00390a009

Source and publish data:

Journal of Organic Chemistry p. 2997 - 2999 (1987)

Update date:2022-08-15

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Authors:

Gavina, Francisco

Costero, Ana M.

Gonzales, Ana M.

Luis, Santiago V.

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Article abstract of DOI:10.1021/jo00390a009

Evidence is presented that demonstrates the existence of free bicyclo<3.3.0>octa-1(5),3,7-triene-2,6-dione, which through an elimination process has been generated from an insoluble polymeric precursor.The diketone can act either as a diene or as a dienophile in pericyclic reactions

Full text of DOI:10.1021/jo00390a009

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