Journal of the American Chemical Society
Page 6 of 7
(12) Wan, X.-K.; Tang, Q.; Yuan, S.-F.; Jiang, D.-e.; Wang, Q.-M.
Au19 nanocluster featuring a V-shaped alkynyl-gold motif. J. Am.
Chem. Soc. 2015, 137, 652-655.
(32) Semagina, N.; Kiwi - Minsker, L. Recent advances in the liq-
uid‐phase synthesis of metal nanostructures with controlled shape and
size for catalysis. Catal. Rev. 2009, 51, 147-217.
1
2
3
4
5
6
7
8
9
(13) Wan, X.-K.; Yuan, S.-F.; Tang, Q.; Jiang, D.-e.; Wang, Q.-M.
Alkynyl-protected Au23 nanocluster: a 12-electron system. Angew.
Chem. Int. Ed. 2015, 54, 5977-5980.
(33) Higaki, T.; Zhou, M.; Lambright, K. J.; Kirschbaum, K.; Sfeir,
M. Y.; Jin, R. Sharp transition from nonmetallic Au246 to metallic Au279
with nascent surface plasmon resonance. J. Am. Chem. Soc. 2018, 140,
5691-5695.
(34) Sakthivel, N. A.; Theivendran, S.; Ganeshraj, V.; Oliver, A. G.;
Dass, A. Crystal structure of faradaurate-279: Au279(SPh-tBu)84 plas-
monic nanocrystal molecules. J. Am. Chem. Soc. 2017, 139, 15450-
15459.
(35) Crystal data for Au110: C444H224Au110F144N2, triclinic space group,
P-1, a = 25.4658(13) Å, b = 25.5043(12) Å, c = 25.6054(12) Å,
α = 67.082(4), β = 85.207(4), γ = 84.085(4)°, V = 15219.0(13) Å3, Z =
1, T = 100 K, 96916 reflections measured, 46469 unique (Rint = 0.0907)
final R1 = 0.0836, wR2 = 0.2392 for 16379 observed reflections
[I >2σ(I)]. CCDC 2015300.
(36) Zeng, J.-L.; Guan, Z.-J.; Du, Y.; Nan, Z.-A.; Lin, Y.-M.; Wang,
Q.-M. Chloride-promoted formation of a bimetallic nanocluster
Au80Ag30 and the total structure determination. J. Am. Chem. Soc. 2016,
138, 7848-7851.
(37) Guan, Z.-J.; Zeng, J.-L.; Yuan, S.-F.; Hu, F.; Lin, Y.-M.; Wang,
Q.-M. Au57Ag53(C≡CPh)40Br12: A large nanocluster with C1 symmetry.
Angew. Chem. Int. Ed. 2018, 57, 5703-5707.
(38) Mingos, D. M. P.; Yau, J.; Menzer, S.; Williams, D. J. A Gold(I)
[2] catene. Angew. Chem. Int. Ed. 1995, 34, 1894-1895.
(39) Yip, S. K.; Cheng, E. C.; Yuan, L. H.; Zhu, N.; Yam, V. W. Su-
pramolecular assembly of luminescent gold(I) alkynylcalix[4]crown-6
complexes with planar η2,η2-coordinated gold(I) centers. Angew. Chem.
Int. Ed. 2004, 43, 4954-4957.
(40) Koshevoy, I. O.; Karttunen, A. J.; Shakirova, J. R.; Melnikov, A.
S.; Haukka, M.; Tunik, S. P.; Pakkanen, T. A. Halide-directed assem-
bly of multicomponent systems: highly ordered Au(I)-Ag(I) molecular
aggregates. Angew. Chem. Int. Ed. 2010, 49, 8864-8866.
(41) Higaki, T.; Zhou, M.; He, G.; House, S. D.; Sfeir, M. Y.; Yang,
J. C.; Jin, R. Anomalous phonon relaxation in Au333(SR)79 nanoparti-
13215-13220.
(42) Levi-Kalisman, Y.; Jadzinsky, P. D.; Kalisman, N.; Tsunoyama,
H.; Tsukuda, T.; Bushnell, D. A.; Kornberg, R. D. Synthesis and char-
acterization of Au102(p-MBA)44 nanoparticles. J. Am. Chem. Soc. 2011,
133, 2976-2982.
(43) Mustalahti, S.; Myllyperkiö, P.; Lahtinen, T.; Salorinne, K.;
Malola, S.; Koivisto, J.; Häkkinen, H.; Pettersson, M. Ultrafast elec-
tronic relaxation and vibrational cooling dynamics of
Au144(SC2H4Ph)60 nanocluster probed by transient mid-IR spectros-
copy. J. Phys. Chem. C 2014, 118, 18233-18239.
(44) Kumara, C.; Zuo, X.; Ilavsky, J.; Chapman, K. W.; Cullen, D. A.;
Dass, A. Super-stable, highly monodisperse plasmonic Faradaurate-
500 nanocrystals with 500 gold atoms: Au~500 (SR)~120. J. Am. Chem.
Soc. 2014, 136, 7410-7417.
(45) Zhou, M.; Higaki, T.; Li, Y.; Zeng, C.; Li, Q.; Sfeir, M. Y.; Jin,
R. Three-stage evolution from nonscalable to scalable optical proper-
ties of thiolate-protected gold nanoclusters. J. Am. Chem. Soc. 2019,
141, 19754-19764.
(46) Higaki, T.; Liu, C.; Zhou, M.; Luo, T. Y.; Rosi, N. L.; Jin, R.
Tailoring the structure of 58-electron gold nanoclusters: Au103S2(S-
Nap)41 and its implications. J. Am. Chem. Soc. 2017, 139, 9994-10001.
(47) Padelford, J. W.; Zhou, M.; Chen, Y.; Jin, R.; Wang, G. Elec-
tronic transitions in highly symmetric Au130 nanoclusters by spectroe-
lectrochemistry and ultrafast spectroscopy. J. Phys. Chem. C 2017, 121,
21217-21224.
(48) Kwak, K.; Thanthirige, V. D.; Pyo, K.; Lee, D.; Ramakrishna, G.
Energy gap law for exciton dynamics in gold cluster molecules. J. Phys.
Chem. Lett. 2017, 8, 4898-4905.
(49) Wu, N. M.; Ng, M.; Yam, V. W. Photochromic benzo[b]phos-
phole alkynylgold(I) complexes with mechanochromic property to
serve as multistimuli-responsive materials. Angew. Chem. Int. Ed. 2019,
58, 3027-3031.
(50) Koshevoy, I. O.; Chang, Y. C.; Karttunen, A. J.; Selivanov, S. I.;
Janis, J.; Haukka, M.; Pakkanen, T.; Tunik, S. P.; Chou, P. T. Intensely
luminescent homoleptic alkynyl decanuclear gold(I) clusters and their
(14) Wang, J.-Q.; Guan, Z.-J.; Liu, W.-D.; Yang, Y.; Wang, Q.-M.
Chiroptical activity enhancement via structural control: the chiral syn-
thesis and reversible interconversion of two intrinsically chiral gold
nanoclusters. J. Am. Chem. Soc. 2019, 141, 2384-2390.
(15) Han, X.-S.; Luan, X.; Su, H.-F.; Li, J.-J.; Yuan, S.-F.; Lei, Z.; Pei,
Y.; Wang, Q.-M. Structure determination of alkynyl-protected gold
nanocluster Au22(tBuC≡C)18 and its thermochromic luminescence. An-
gew. Chem. Int. Ed. 2020, 59, 2309-2312.
(16) Li, J.-J.; Guan, Z.-J.; Lei, Z.; Hu, F.; Wang, Q.-M. Same magic
number but different arrangement: alkynyl-protected Au25 with D3
symmetry. Angew. Chem. Int. Ed. 2019, 58, 1083-1087.
(17) Wan, X.-K.; Guan, Z.-J.; Wang, Q.-M. Homoleptic alkynyl-pro-
tected gold nanoclusters: Au44(PhC≡C)28 and Au36(PhC≡C)24. Angew.
Chem. Int. Ed. 2017, 56, 11494-11497.
(18) Lei, Z.; Li, J.-J.; Wan, X.-K.; Zhang, W.-H.; Wang, Q.-M. Isola-
tion and total structure determination of an all-alkynyl-protected gold
nanocluster Au144. Angew. Chem. Int. Ed. 2018, 57, 8639-8643.
(19) Yu, Y.; Luo, Z.; Chevrier, D. M.; Leong, D. T.; Zhang, P.; Jiang,
D. e.; Xie, J. Identification of a highly luminescent Au22(SG)18
nanocluster. J. Am. Chem. Soc. 2014, 136, 1246-1249.
(20) Zhu, M.; Aikens, C. M.; Hollander, F. J.; Schatz, G. C.; Jin, R.
Correlating the crystal structure of a thiol-protected Au25 cluster and
optical properties. J. Am. Chem. Soc. 2008, 130, 5883-5885.
(21) Zeng, C.; Qian, H.; Li, T.; Li, G.; Rosi, N. L.; Yoon, B.; Barnett,
R. N.; Whetten, R. L.; Landman, U.; Jin, R. Total structure and elec-
tronic properties of the gold nanocrystal Au36(SR)24. Angew. Chem. Int.
Ed. 2012, 51, 13114-13118.
(22) Zeng, C.; Chen, Y.; Li, G.; Jin, R. Synthesis of a Au44(SR)28
nanocluster: structure prediction and evolution from Au28(SR)20,
Au36(SR)24 to Au44(SR)28. Chem. Commun. 2014, 50, 55-57.
(23) Yan, N.; Xia, N.; Liao, L.; Zhu, M.; Jin, F.; Jin, R.; Wu, Z. Un-
raveling the long-pursued Au144 structure by X-ray crystallography. Sci.
Adv. 2018, 4, eaat7259.
(24) Maity, P.; Tsunoyama, H.; Yamauchi, M.; Xie, S.; Tsukuda, T.
Organogold clusters protected by phenylacetylene. J. Am. Chem. Soc.
2011, 133, 20123-20125.
(25) Lei, Z.; Wan, X.-K.; Yuan, S.-F.; Guan, Z.-J.; Wang, Q.-M. Al-
kynyl approach toward the protection of metal nanoclusters. Acc. Chem.
Res. 2018, 51, 2465-2474.
(26) Storhoff, J. J.; Lazarides, A. A.; Mucic, R. C.; Mirkin, C. A.;
Letsinger, R. L.; Schatz, G. C. What controls the optical properties of
DNA-linked gold nanoparticle assemblies? J. Am. Chem. Soc. 2000,
122, 4640-4650.
(27) Negishi, Y.; Nakazaki, T.; Malola, S.; Takano, S.; Niihori, Y.;
Kurashige, W.; Yamazoe, S.; Tsukuda, T.; Hakkinen, H. A critical size
for emergence of nonbulk electronic and geometric structures in dodec-
anethiolate-protected Au clusters. J. Am. Chem. Soc. 2015, 137, 1206-
1212.
(28) Xu, W. W.; Li, Y.; Gao, Y.; Zeng, X. C. Unraveling a generic
growth pattern in structure evolution of thiolate-protected gold
nanoclusters. Nanoscale 2016, 8, 7396-7401.
(29) Ma, Z.; Wang, P.; Pei, Y. Geometric structure, electronic struc-
ture and optical absorption properties of one-dimensional thiolate-pro-
tected gold clusters containing a quasi-face-centered-cubic (quasi-fcc)
Au-core: a density-functional theoretical study. Nanoscale 2016, 8,
17044-17054.
(30) Liao, L.; Zhuang, S.; Wang, P.; Xu, Y.; Yan, N.; Dong, H.; Wang,
C.; Zhao, Y.; Xia, N.; Li, J.; Deng, H.; Pei, Y.; Tian, S. K.; Wu, Z.
Quasi-dual-packed-kerneled Au49 (2,4-DMBT)27 nanoclusters and the
influence of kernel packing on the electrochemical gap. Angew. Chem.
Int. Ed. 2017, 56, 12644-12648.
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
46
47
48
49
50
51
52
53
54
55
56
57
58
59
60
(31) Zhuang, S.; Liao, L.; Yuan, J.; Xia, N.; Zhao, Y.; Wang, C.; Gan,
Z.; Yan, N.; He, L.; Li, J.; Deng, H.; Guan, Z.; Yang, J.; Wu, Z. Fcc
versus non-fcc structural isomerism of gold nanoparticles with kernel
atom packing dependent photoluminescence. Angew. Chem. Int. Ed.
2019, 58, 4510-4514.
6
ACS Paragon Plus Environment