Tetrahedron Letters p. 1609 - 1612 (1994)
Update date:2022-08-17
Topics:
Lucke, Andrew J.
Young, David J.
The reaction of 2-methylcyclopropylcarbinyltrimethylstannane 1 in chloroform with the electrophiles sulphur dioxide, trifluoroacetic acid, and iodine proceeds preferentially with ring cleavage and addition at the unsubstituted cyclopropyl methylene.Iodination and acidolysis in methanol proceeds exclusively with tin-methyl bond cleavage.
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