Chemistry Letters p. 141 - 144 (1985)
Update date:2022-08-31
Topics:
Yanagida, Shozo
Kizumoto, Hirotoshi
Ishimaru, Yoshiteru
Pac, Chyongjin
Sakurai, Hiroshi
Nonmetallized ZnS catalizes efficiently the photochemical conversion of primary amines to secondary amines with liberation of ammonia under irradiation of the UV light of λ>290 nm.The conversion is interpreted as due to the two-hole-oxidation of primary amines to Schiff bases and their two-electron-reduction to secondary amines by the photogenerated electrons in ZnS.
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