Chemistry Letters p. 2127 - 2130 (1986)
Update date:2022-08-11
Topics:
Maeda, Yasuaki
Fujio, Yoshifumi
Munemori, Makoto
Formation of alkyl nitrite from alcohol and NO2 was very fast on a Pyrex glass surface cleaned with chromic acid mixture.The reaction was practically zero order with respect to NO2.The rate constant was (1.7 +/- 0.08)*10E-18 cm3*molecule-1*s-1 for methyl nitrile formation and the apparent activation energy was -53.5 kJ*mol-1.
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