Redox Behavior of Simple Vitamin B12 Model Complexes with Cobalt-Carbon Bonds and Catalytic Carbon-Skeleton Rearrangements

DOI: 10.1246/cl.1988.835

Source and publish data:

Chemistry Letters p. 835 - 838 (1988)

Update date:2022-08-16

Topics:

Authors:

Murakami, Yukito

Hisaeda, Yoshio

Fan, Sheng-Di

Matsuda, Yoshihisa

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Article abstract of DOI:10.1246/cl.1988.835

The cobalt complex of 2,10-diethyl-3,9-dipropyl-1,4,8,11-tetraaazaundeca-1,3,8,10-tetraene-1,11-diol catalyzed electrolyses of alkyl halides with electron-withdrawing groups at the β-position to afford rearrangement products via oxidation of the corresponding dialkylated complexes as intermediates.

Full text of DOI:10.1246/cl.1988.835

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