Journal of the Chemical Society. Chemical communications p. 728 - 729 (1980)
Update date:2022-08-05
Topics:
Alborz, Manoochehr
Douglas, Kenneth T.
The Broensted leaving group (βlg) plot for the alkaline hydrolysis of fluorene-9-carboxylate esters in the pH region corresponding to the existence of the ester anion shows a minimum flanked by a region of high negative βlg (-1.01), corresponding to an E1cb pathway and, for esters of pKlg >9.5, a region of positive βlg (+0.11).
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