Tetrahedron Letters p. 9201 - 9204 (1999)
Update date:2022-08-17
Topics:
Barton, Derek H. R.
Jacob, Marc
Peralez, Eric
A simple water soluble diselenide derivative 1 shows radical scavenger properties towards alkyl and hydroxyl radicals (k3 (0°C)=6.8x108 M-1 s-1) in Fenton-type chemistry. The reaction rate between produced alkyl radicals 2 and the diselenide overwhelms self-termination and halogen transfer reactions.
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