Chemistry Letters p. 1237 - 1238 (1987)
Update date:2022-08-11
Topics:
Kosugi, Masanori
Ohashi, Kenji
Akuzawa, Kazuko
Kawazoe, Takashi
Sano, Hiroshi
Migita, Toshihoko
In the presence of Pd(0) complexes, 2-ethoxy-2-propenyl diethyl phosphate was found to react with organotins to give the corresponding coupling products, showing to be a more efficient halo acetone equivalent compared with the corresponding acetate or carbonate.Reaction with tin enolates gave the 1,4-diketone in moderate to good yields.
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