Journal of the Chemical Society, Dalton Transactions p. 3061 - 3066 (1994)
Update date:2022-08-17
Topics:
MacDougall, Joanna K.
Simpson, Michael C.
Cole-Hamilton, David J.
Products from the hydrocarbonylation of hex-1-ene or prop-2-en-1-ol using H2-CO or D2-CO in EtOH or EtOD have been analysed using 13C NMR techniques.Where there are up to four isotopomers in the products, analysis of β-shifted resonances in the 13C-<1H> NMR spectrum can give enough information for quantification of all isotopomers.Using prop-2-en-1-ol, D2-CO and EtOH, the 2-methylpropanol produced is a mixture of 16 different isotopomers.These can be individually quantified by analysis of the 13C-<1H, 2D> NMR spectrum.In particular, the resonance from the methyl C atom shows β and γ shifts, the latter being different for different types of γ-D atom.These analytical methods are shown to be superior to other possibilities including 1H NMR and mass spectrometry.
View MoreContact:+31-24-3886056
Address:Binderskampweg 29 Unit 36
Shenzhen ZheYi Chemicals Co.,LTD(Shanghai Branch)
Contact:+86-21-54159691
Address:Room1002,Building No.2, Lane 98 Bixiu Road,Minhang District, Shanghai,China 201100
Contact:
Address:308# dongwu avenue dongxihu district wuhan city
jiangsu haian chemical co.,ltd.
Contact:86-513-15851283853
Address:No.99,Changjiang West Road,Haian County,Jiangsu Province,China
Shanghai Kefu Chemical Co.,Ltd.
Contact:+86-21-34616196
Address:Room601-602, Xuhui Business Building, No.168, Yude Road, Shanghai
Doi:10.1016/j.ica.2019.02.017
(2019)Doi:10.1039/TF9262100569
(1925)Doi:10.1016/j.jorganchem.2019.07.003
(2019)Doi:10.1016/0022-4596(81)90308-X
(1981)Doi:10.1021/om500878f
(2014)Doi:10.1134/S0965544117050103
()
