Journal of the Chemical Society. Chemical communications p. 1409 - 1410 (1986)
Update date:2022-08-11
Topics:
Dowd, Paul
Hershline, Roger
The model rearrangement mimicking the coenzyme B12-dependent, enzyme-catalysed interconversion of α-methyleneglutaric acid with methylitaconic acid has been carried out with a carbon-13 label demonstrating beyond question that the acrylate group is the migrating group in the model as it is in the enzyme-catalysed rearrangement.
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