Benzenehexathiol as a Template Rim for a Golden Wheel: Synthesis and Structure of 6>

DOI: 10.1039/DT9940002333

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 2333 - 2334 (1994)

Update date:2022-08-11

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Authors:

Yip, Hon Kay

Schier, Annette

Riede, Juergen

Schmidbaur, Hubert

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Article abstract of DOI:10.1039/DT9940002333

The reaction of benzenehexathiol, C6(SH)6, with in the presence of triethylamine gave the hexanuclear gold(I) compound <6> whose structure has been determined; the hexagon of the central benzene carbon atoms is surrounded by a hexagon of sulfur atoms, followed by a hexagon of gold atoms and the wheel-like structure is completed by six peripheral phosphine ligands with interlocked aryl groups.

Full text of DOI:10.1039/DT9940002333

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