TBAHF2 and TBAH2F3 as Activating Agents of Organosilanes

DOI: 10.1055/s-1997-3276

Source and publish data:

Synlett p. 693 - 694 (1997)

Update date:2022-08-17

Topics:

Authors:

Mori, Atsunori

Fujita, Akinori

Ikegashira, Kazutaka

Nishihara, Yasushi

Hiyama, Tamejiro

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Article abstract of DOI:10.1055/s-1997-3276

The fluoride reagents, TBAH₂F₃ and TBAHF₂ (TBA: tetrabutylammonium), are found to catalyze the reactions of hexamethyldisilane with 1,3-dienes, aliphatic aldehydes, and aromatic aldehydes to give 1,4-disilyl-2-butenes, α-silyl alcohols and pinacols, respectively. Using an equimolar amount of TBAHF₂ and disilanes, reduction of carbonyl compounds occurs in place of the silyl group addition.

Full text of DOI:10.1055/s-1997-3276

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