TBAHF2 and TBAH2F3 as Activating Agents of Organosilanes

DOI: 10.1055/s-1997-3276

Source and publish data:

Synlett p. 693 - 694 (1997)

Update date:2022-08-17

Topics:

Authors:

Mori, Atsunori

Fujita, Akinori

Ikegashira, Kazutaka

Nishihara, Yasushi

Hiyama, Tamejiro

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1055/s-1997-3276

The fluoride reagents, TBAH₂F₃ and TBAHF₂ (TBA: tetrabutylammonium), are found to catalyze the reactions of hexamethyldisilane with 1,3-dienes, aliphatic aldehydes, and aromatic aldehydes to give 1,4-disilyl-2-butenes, α-silyl alcohols and pinacols, respectively. Using an equimolar amount of TBAHF₂ and disilanes, reduction of carbonyl compounds occurs in place of the silyl group addition.

Full text of DOI:10.1055/s-1997-3276

Products guided by the article

Product name:1-Octanol

Cas No:111-87-5

R&D Labs maybe for 111-87-5

Ningbo J&S Botanics Inc.

Contact:86-574-26865651

Address:529 YuanBaoShan Road, Beilun District
Yueyang Hudex Pharmaceuticals Ltd.

Contact:0730-8748800

Address:Wujiang Bridge，Yueyang Economy & Technology Development Zone
Suzhou Wedo Chemicals Co., Ltd.

Contact:86 512 58100425

Address:Zonger Road, DongSha Industry Park , Zhangjiagang, Jiangsu, China
ClickChem Technology Co., Limited

Contact:+86-0310-6519966/0531-52893837

Address:No.750 Shunhua Road, High-Tech Zone, Jinan city, Shandong China
FREEBARQUE DEVELOPMENT GROUP LIMITED

Contact:+86(0)10-5109 5335 or 5109 5345

Address:Room602,Block1-B,LINGDI OFFICE,NO.13 BEIYUAN ROAD

Relevant to this article

Doi:10.1002/hlca.19750580204
(1975)
Investigation on mechanism of catalysis by Pt-LiCoO₂ for hydrolysis of sodium borohydride using X-ray absorption

Doi:10.1021/jp075592n
(2008)
Dimethyl 2,6-dimethyl-4-(3-nitrophenyl)-pyridine-3,5-dicarboxylate, diethyl 2,6-dimethyl-4-(3-nitrophenyl)-1,4-dihydropyridine-3,5-dicarboxylate, and diethyl 2,6-dimethyl-4-(3-nitrophenyl)pyridine-3,5-dicarboxylate

Doi:10.1107/S0108270196000091
(1996)
Targeting the subpocket in xanthine oxidase: Design, synthesis, and biological evaluation of 2-[4-alkoxy-3-(1H-tetrazol-1-yl) phenyl]-6-oxo-1,6-dihydropyrimidine-5-carboxylic acid derivatives

Doi:10.1016/j.ejmech.2019.07.062
(2019)
High-throughput method for on-target performic acid oxidation of MALDI-deposited samples

Doi:10.1002/jms.1699
(2010)
Cascade Michael addition/cycloketalization of cyclic 1,3-dicarbonyl compounds: Important role of the tethered alcohol of α,β-unsaturated carbonyl compounds on reaction rate and regioselectivity

Doi:10.1021/jo501604e
(2014)

Article Doi