Chemistry Letters p. 1393 - 1396 (1986)
Update date:2022-08-29
Topics:
Setsune, Jun-ichiro
Fujiwara, Takashi
Murakami, Kazutoshi
Mizuta, Yasufumi
Kitao, Teijiro
N,N'-Oxalyl and N,N'-malonyl derivatives of indigo and 6,6'-di-t-butylindigo were reduced with high quantum efficiencies to their semi-reduced radicals by visible light irradiation in the presence of tertiary amines.These semi-reduced radicals were reversibly autoxidized and thus oxidative dealkylation of tertiary amines was catalyzed photochemically by these indigos.
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