Synthetic Communications p. 2527 - 2532 (1997)
Update date:2022-08-29
Topics:
Lin, Ji-Mao
Zhou, Ai-Min
Zhang, Hui
Hao, Ai-You
In the presence of iodine, magnesium reacts with alcohols to give magnesium alkoxides, which are treated with octamethylcyclotetrasiloxane to produce dialkoxydimethylsilanes. Similarly, magnesium reacts with 1,3, 1,4 and 1,5 diols and then with octamethylcyclotetrasiloxane, producing 2, 2- dimethyl-1 3-dioxa-2-silacyclo compounds.
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