Journal of Organometallic Chemistry p. 145 - 154 (1981)
Update date:2022-08-11
Topics:
Gusel'nikov, L. E.
Sokolova, V. M.
Vonina, E. A.
Zalikin, V. G.
Nametkin, N. S.
et al.
Pyrolisis of 3,3-diethyl-2,4-dimethyl-3-silathietane (I) has been studied at temperatures from 300 to 530 deg C using the pulse pyolytic GC-MS method.Decomposition of I proceeds with the elimination of ethane, ethylene, propylene, butadiene, cis- and trans-but-2-ene, and also with the loss of atomic sulphur.Isomerization into sulphur-containing unsaturated compounds is the main transformation process of I.The intermediacy of 1,1-diethyl-2-methyl-1-silaethylene and diethylsilathione is also discussed.
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