Enolate and Other Carbon Nucleophile Alkylation Reactions Using 1,2-Cyclic Sulfates as Terminal Epoxide Equivalents

Article abstract of DOI:10.1021/jo00082a005

Enolates of esters and amides as well as α-sulfonyl-, α-cyano-, and α-phosphonyl-substituted anions react with cyclic sulfate 1 to give hydroxylated products arising from nucleophilic attack, on this terminal epoxide equivalent, at the primary carbon.