SYNTHESIS OF MONO- AND 1,4-DICARBONYL COMPOUNDS BASED ON THE OXYGENATION OF PHOSPHONATE CARBANIONS. SYNTHESIS OF DIHYDROJASMONE, ALLETHRONE AND METHYLENOMYCIN B

DOI: 10.1016/S0040-4039(01)81212-0

Source and publish data:

Tetrahedron Letters p. 2489 - 2492 (1984)

Update date:2022-08-11

Topics:

Authors:

Mikolajczyk, Marian

Midura, Wanda

Grzejszczak, Slawomir

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Article abstract of DOI:10.1016/S0040-4039(01)81212-0

Oxidation of the α-alkylthio-substituted phosphonate carbanions was found to give the corresponding carbonyl compounds.A new synthesis of 1,4-dicarbonyl systems involving the oxygenation of phosphonate carbanions as a key step is described.Total synthesis of dihydrojasmone and allethrone and formal synthesis of methylenomycin B is reported.

Full text of DOI:10.1016/S0040-4039(01)81212-0

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