Journal of the Chemical Society. Chemical communications p. 1831 - 1832 (1995)
Update date:2022-08-28
Topics:
Adam, Waldemar
Briviba, Karlis
Duschek, Frank
Golsch, Dieter
Kiefer, Wolfgang
Sies, Helmut
4-Dimethylaminopyridine-N-oxide 2 and 2',3',5'-triacetyladenosine-N1-oxide 4 are partially deoxygenated by dimethyldioxirane (DMD) to the corresponding amines 1 and 3; the formation of singlet oxygen suggests a polar rather than a radical mechanism, in which we propose SN2 attack of the N-oxide on the dioxirane peroxide bond.
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