Tetrahedron p. 9893 - 9908 (1994)
Update date:2022-08-11
Topics:
Searle, Philip A.
Molinski, Tadeusz F.
Eight new compounds were isolated from a Western Australian sponge Spongia sp., including 12-hydroxyambliofuran (5), its acetate ester 6, five new tetracyclic diterpenes 7 -bd11 and the epoxyfuranosesterterpene carboxylic acid 12. Compounds 5 and 6, each isolated as a 3:1 mixture of enantiomers as determined by a modified Mosher's ester method and chiral lanthanide NMR shift studies, are rare examples of scalemic marine natural products.
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