Investigation on Factors Ruling Catalytic Efficiency and Chemical Stability of Mn(III) Porphyrins in HOCl Olefin Epoxidation: Conditions for Practical Applications

Article abstract of DOI:10.1021/jo00269a021

The use of stable Mn(III) porphyrins (P), e.g. 2-4, and of imidazole or pyridine axial ligands (L), 8-10, entirely soluble in the organic phase has allowed an extensive investigation of the factors ruling the catalytic activity of porphyrins in the olefin