Synthesis of the β-lactone esterase inhibitor valilactone using πallyltricarbonyliron lactone complexes

DOI: 10.1016/S0040-4039(00)78809-5

Source and publish data:

Tetrahedron Letters p. 2651 - 2654 (1991)

Update date:2022-08-11

Topics:

Authors:

Bates, Roderick W.

Fernandez-Moro, Rosalina

Ley, Steven V.

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Article abstract of DOI:10.1016/S0040-4039(00)78809-5

Synthesis of the esterase inhibitor valilactone (1) is reported employing the oxidation of π-allyltricarbonyliron lactone complexes with ceric ammonium nitrate to afford the inherent β-lactone ring.

Full text of DOI:10.1016/S0040-4039(00)78809-5

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