A New Preparation of Lanthanide Alkoxides, and some Application in Catalysis

DOI: 10.1016/S0040-4039(00)79922-9

Source and publish data:

Tetrahedron Letters p. 2355 - 2358 (1991)

Update date:2022-08-17

Topics:

Authors:

Lebrun, Alain

Namy, Jean-Louis

Kagan, Henri B.

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Article abstract of DOI:10.1016/S0040-4039(00)79922-9

A new route to lanthanide tris(alkoxides) is described.These coumpounds are prepared by reaction of n-BuLi with corresponding adducts LnCl3, (3-4 ROH) that are obtained from hydrated LnCl3.They are efficient as catalysts in epoxidation of allylic alcohols by TBHP and in meerwein-Ponndorf-Verley-Oppenauer reactions.

Full text of DOI:10.1016/S0040-4039(00)79922-9

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