Tetrahedron Letters p. 2355 - 2358 (1991)
Update date:2022-08-17
Topics:
Lebrun, Alain
Namy, Jean-Louis
Kagan, Henri B.
A new route to lanthanide tris(alkoxides) is described.These coumpounds are prepared by reaction of n-BuLi with corresponding adducts LnCl3, (3-4 ROH) that are obtained from hydrated LnCl3.They are efficient as catalysts in epoxidation of allylic alcohols by TBHP and in meerwein-Ponndorf-Verley-Oppenauer reactions.
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