Journal of Mass Spectrometry p. 1653 - 1662 (1995)
Update date:2022-08-10
Topics:
Olmstead, William N.
Brauman, John I.
Displacement reactions of each of a variety of anionic nucleophiles reacting with each of a variety of neutrals have been studied by pulsed ion cyclotron resonance (ICR) spectroscopy.Rate constants for these reactions are interpreted in terms of a three-step reaction sequence.RRKM calculations are used to obtain information about the energy of transition states.The origin of the barrier to reaction in solution is discussed.
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