Journal of the Chemical Society - Faraday Transactions p. 1981 - 1984 (1996)
Update date:2022-08-11
Topics:
Matsumura, Yasuyuki
Moffat, John B.
On hydroxyapatite of stoichiometric composition (Ca/P = 1.65), methanol decomposes at 600°C, in the absence of oxygen, to produce predominantly carbon monoxide. As the Ca/P ratio decreases, the selectivities to formaldehyde and dimethyl ether increase to ca. 80% at a value of Ca/P equal to 1.51. IR spectra show that methoxy groups are formed on the surface of both the stoichiometric and non-stoichiometric catalysts. Both IR and temperature-programmed desorption experiments suggest that for the decomposition of methanol, acidic sites are required for the dissociative adsorption whereas basic sites facilitate the C-H bond scission via carboxylate groups and the consequent formation of CO and H2.
View MoreZibo Hangyu Biotechnology Development Co., Ltd
Contact:86-15965530500
Address:Room1701, Tianxing Building,Licheng district, jinan, Shandong, China
Wuhan Better Organic Technology Inc.
Contact:13307163183
Address:Wuhan Economic&Technology Development Zone, Hubei
Shandong Yuanli Science and Technology Co., Ltd.
Contact:86-0536-6777557
Address:Zhuliu Industiral Park,Changle County
Hunan Zhongqi Pharmaceutical Co., Ltd
website:http://www.hnzqzy.com
Contact:0730-8722288 13807308622
Address:Wanjiafan Road ,Yueyang Economic And Technological Development Zone ,Hunan,PRC
Contact:13813902930 025-52714267
Address:20 Fengji Road, Yuhua Economic Development Zone, Nanjing, Jiangsu, P. R. China
Doi:10.1016/j.ejps.2012.02.017
(2012)Doi:10.1039/tf9635901619
(1963)Doi:10.1111/j.1751-1097.1997.tb08546.x
(1997)Doi:10.1016/0022-328X(89)85418-X
(1989)Doi:10.1039/b616922h
(2007)Doi:10.1055/s-1997-3239
(1997)
