An unexpected elimination of cyclopentadienide anion in the reaction of silacyclohexadienes with a bulky aryllithium

DOI: 10.1246/cl.1998.687

Source and publish data:

Chemistry Letters p. 687 - 688 (1998)

Update date:2022-08-29

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Authors:

Wakita, Keiji

Tokitoh, Norihiro

Okazaki, Renji

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Article abstract of DOI:10.1246/cl.1998.687

The reaction of silacyclohexadienes with an extremely hindered aryllithium, TbtLi (Tbt = 2,4,6-tris[bis(trimethylsilyl)-methyl]phenyl), gave no expected Tbt-substituted silacyclohexadienes but trihydrosilane, TbtSiH₃, via the elimination of cyc

Full text of DOI:10.1246/cl.1998.687

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Product name:2,4,6-tris(bis(trimethylsilyl)methyl)benzene

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