Synthesis of o-arylenedizinc compounds from 1-Iodo-2- trifluoromethylsulfonyloxybenzenes and Zinc Powder and their synthetic application

DOI: 10.1016/S0040-4039(98)01867-X

Source and publish data:

Tetrahedron Letters p. 8667 - 8668 (1998)

Update date:2022-08-23

Topics:

Authors:

Amano, Masayuki

Saiga, Akihiro

Ikegami, Ryo

Ogata, Takeshi

Takagi, Kentaro

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Article abstract of DOI:10.1016/S0040-4039(98)01867-X

1-Iodo-2-trifluoromethylsulfonyloxybenzenes readily reacted with Zn powder to yield o-arylenedizinc compounds, efficient synthetic equivalents of o-arylene dianions in Pd(0)-catalyzed cross-coupling reactions, wherein the novel insertion of Zn powder into the C-O bond of aryl triflates took place.

Full text of DOI:10.1016/S0040-4039(98)01867-X

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Product name:1,2-DIBENZOYLBENZENE

Cas No:1159-86-0

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Baoding City Light Industry And Textiles Imp.& Exp. Corp. Chemical Department.

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