Quantum yields of I(2P1/2) for CF3I, C2F5I, i-C3F7I, n-C3F7I, n-C6F13I, and 1,2-C2F4I2 at 308 and 248 nm

Article abstract of DOI:10.1063/1.445523

A new method is applied to measure the wavelength-resolved quantum yields of I(²P_1/2) for six molecules relevant to the iodine I(²P_1/2) atoms and accounts for the strong exciplex emission, also at 1.3 μm, from the I(²P_1/2)-iodide molecules.In addition, digital processing is used to correct for noise, quenching, and the detector rise time.These features avoided the shortcomings of previous measurements.The following molecules were investigated: CF3I, C2F5I, i-C3F7I, n-C3F7I, n-C6F13I, and 1,2-C2F4I2.All six iodides present high yields of I(²P_1/2) at the pumping wavelength of 308 and 248 nm used.The high I(²P_1/2) yields for the molecules n-C6F13I and 1,2-C2F4I2 are reported for the first time.

Full text of DOI:10.1063/1.445523

Quantum yields of I(2 P 1/2) for CF3I, C2F5I, iC3F7I, nC3F7I, nC6F13I, and 1,2C2F4I2 at
08 and 248 nm
3
Edgardo Gerck
Citation: The Journal of Chemical Physics 79, 311 (1983); doi: 10.1063/1.445523
View online: http://dx.doi.org/10.1063/1.445523
View Table of Contents: http://scitation.aip.org/content/aip/journal/jcp/79/1?ver=pdfcov
Published by the AIP Publishing
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This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
42.157.15.116 On: Wed, 03 Dec 2014 17:35:22
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This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
42.157.15.116 On: Wed, 03 Dec 2014 17:35:22
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This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
42.157.15.116 On: Wed, 03 Dec 2014 17:35:22
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This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
42.157.15.116 On: Wed, 03 Dec 2014 17:35:22
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This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
42.157.15.116 On: Wed, 03 Dec 2014 17:35:22
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