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Conclusions
In conclusion, we have prepared and studied a novel light-
harvesting BODIPY–porphyrin ligand and its corresponding
carbonyl ruthenium(II) complex, which exhibits a broad absorp-
tion of visible light using both the porphyrin core and antennae
chromophores. Under visible light irradiation, a highly efficient
decarbonylation reaction of 1 and the formation of a more reactive
trans-dioxoruthenium(VI) species were observed, indicating a photo-
induced energy transfer from the BODIPY to the metalloporphyrin
center. Notably, the ruthenium BODIPY–porphyrin complex has
demonstrated a remarkable light acceleration effect on the selective
sulfide oxidation and alkene epoxidation using PhI(OAc)2 and
Cl2pyNO as terminal oxidants, respectively. The findings in this
work suggest that porphyrin–BODIPY conjugated metal complexes
are potentially useful for visible light-promoted catalytic oxidations.
Further investigation of substrate scope, optimization of reaction
conditions, other inexpensive and environmentally friendly oxygen
sources, and their oxidation mechanisms are currently underway in
our laboratory.
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Author contributions
Conceptualization: R. Zhang. Investigation and experiments:
J. Malone, S. Klaine, C. Alcantar and F. Bratcher: Writing-Original
draft preparation: S. Klaine and R. Zhang. Writing-Reviewing and
Editing; R. Zhang and all others contributed. Project administra-
tion: R. Zhang.
Conflicts of interest
There are no conflicts to declare.
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Acknowledgements
This research is supported by the National Science Foundation
(CHE1764315). S. Klaine, C. Alcantar and F. Bratcher are greatly
thankful for internal grants (FUSE and GSRG) from the WKU
Office of Research and Graduate Studies.
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4984 | New J. Chem., 2021, 45, 4977À4985
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