CHLOROTRIMETHYLSILANE PROMOTED ASYMMETRIC MICHAEL REACTION OF CHIRAL ENAMINES OF α-ALKYL β-KETO ESTERS

DOI: 10.1016/S0040-4039(00)96933-8

Source and publish data:

Tetrahedron Letters p. 6637 - 6640 (1987)

Update date:2022-08-30

Topics:

Authors:

Tomioka, Kiyoshi

Seo, Wonjun

Ando, Kaori

Koga, Kenji

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Article abstract of DOI:10.1016/S0040-4039(00)96933-8

By the promotion of chlorotrimethylsilane, asymmetric Michael reaction of the chiral enamines (2) of α-alkyl β-keto esters (1) with methyl vinyl ketone and ethyl acrylate proceeded to afford, after hydrolysis, either enantiomer of the corresponding adduct

Full text of DOI:10.1016/S0040-4039(00)96933-8

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