A Stereospecific Synthesis of Trisubstituted Alkenes via Hydridation of Dialkylhaloboranes Followed by Hydroboration-Iodination of Internal Alkynes

DOI: 10.1021/jo00340a045

Source and publish data:

Journal of Organic Chemistry p. 171 - 173 (1982)

Update date:2022-08-25

Topics:

Authors:

Brown, Herbert C.

Basavaiah, D.

Kulkarni, Surendra U.

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Article abstract of DOI:10.1021/jo00340a045

Dialkylvinylboranes, prepared conveniently via the hydridation of dialkylhaloboranes in the presence of an internal alkyne, react with iodine under basic conditions to produce trisubstituted alkenes of established stereochemistry, providing a general synthesis of trisubstituted alkenes with unambiguous stereochemistry.

Full text of DOI:10.1021/jo00340a045

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