THE REGIOSPECIFIC FORMATION AND REACTIONS OF 4-LITHIO-2-(t-BUTYLDIMETHYLSILYL)-3-(HYDROXYMETHYL)FURAN: AN APPROACH TO 3,4-DISUBSTITUTED FURANS

DOI: 10.1016/S0040-4039(00)80267-1

Source and publish data:

Tetrahedron Letters p. 1247 - 1250 (1988)

Update date:2022-08-11

Topics:

Authors:

Bures, J. Edward

Keay, A. Brian

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Article abstract of DOI:10.1016/S0040-4039(00)80267-1

4-Lithio-2-(t-butyldimethylsilyl)-3-(hydroxymethyl)furan, generated by treating 2-(t-butyldimethylsilyl)-3-(hydroxymethyl)furan 2 with 2.2 equivalents of n-butyllithium (DME/0 deg C/15 min), is trapped by a variety of electrophiles to produce, after desilylation, 3,4-disubstituted furans in good to moderate yields.

Full text of DOI:10.1016/S0040-4039(00)80267-1

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