Journal of Organic Chemistry p. 3356 - 3358 (1984)
Update date:2022-08-11
Topics:
Peacock, Nancy J.
Schuster, Gary B.
The reaction between 1,1-diphenylethylene (DPE) and 2,3,5,6-tetrafluoro-7,7,8,8-tetracyanoquinodimethane (TCNQF4) in air-saturated acetic acid mimics the photochemical electron-transfer oxidation of this olefin.However, the mechanism of the photooxidation is apparently quite different from that observed for the TCNQF4-mediated reaction.In the latter case a peroxide-initiated free-radical oxidation occurs.
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