Synthetic Communications p. 2281 - 2291 (1999)
Update date:2022-08-16
Topics:
Giurg, Miroslaw
Mlochowski, Jacek
Cycloalkanones (1) oxidized with 30% hydrogen peroxide in the presence of poly(bisanthracenyl) diselenide (5b) as catalyst, produce cycloalkanecarboxylic acids (2) having one carbon atom less in the ring that the substrate. Although preparative yield of acids 2 does not exceed 60% the reaction can be applied as a simple way for synthesis of cycloalkanecarboxylic acids with five to seven-membered ring.
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