Facile and Regioselective Epoxidations of Olefins with a Peroxysulfur Intermediate Generated from Superoxide Anion (O2-.) and Nitrobenzenesulfonyl Chlorides

DOI: 10.1021/jo00157a045

Source and publish data:

Journal of Organic Chemistry p. 1562 - 1564 (1983)

Update date:2022-08-17

Topics:

Authors:

Kim, Yong Hae

Chung, Bong Chul

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00157a045

A peroxysulfur intermediate generated from the reaction of o- or p-nitrobenzenesulfonyl chloride with superoxide anion (O2-.) is found to be an excellent oxidizing reagent for the facile and regioselective epoxidation of olefins at -35 deg C.

Full text of DOI:10.1021/jo00157a045

Products guided by the article

Product name:(+)-LIMONENE OXIDE 97% MIXTURE OF CIS&

Cas No:1195-92-2

R&D Labs maybe for 1195-92-2

Hangzhou Haichem Co.,Ltd.

Contact:+86-571-86025531 / 86024803

Address:1218-24 Guangyin Mansion,42 Fengqi East Road
HANGZHOU PANYU CHEMICAL CO.,LIMITED

Contact:+86-571-86578491

Address:Rm 605, NO.1870 Binsheng Road,Binjiang Dist, Hangzhou, China
H&Y International Group Ltd

Contact:+86-571-86491666

Address:SHI XIANG ROAD
NEW FORTUNE INDUSTRIAL CO.,LTD.

website:http://newfortune.lookchem.com/

Contact:+86-25-8645-9456

Address:C4-105 GREEN ISLAND FLOWER TOWN
Tosta Enterprise Co., Ltd.

Contact:+86-134-5286-9121

Address:Add: Wing Tuck Commercial Centre, 177-183 Wing Lok Street, Hong Kong,

Relevant to this article

Development of a Selective CDK7 Covalent Inhibitor Reveals Predominant Cell-Cycle Phenotype

Doi:10.1016/j.chembiol.2019.02.012
(2019)
Nitro-substituted tetrahydroindolizines and homologs: Design, kinetics, and mechanism of α-glucosidase inhibition

Doi:10.1016/j.bmcl.2017.07.068
(2017)
Intermolecular carbene S-H insertion catalysed by engineered myoglobin-based catalysts

Doi:10.1039/c5sc00080g
(2015)
Direct Determination of the Number of Electrons Needed to Reduce Coenzyme F430 Pentamethyl Ester to the Ni(I) Species Exhibiting the Electron Paramagnetic Resonance and Ultraviolet-Visible Spectra Characteristic for the MCR_redl State of Methyl-coenzyme M Reductase

Doi:10.1021/ja037862v
(2003)
Catalytic Conversion of Alcohols to Carboxylic Acid Salts and Hydrogen with Alkaline Water

Doi:10.1021/acscatal.6b03259
(2017)
Family-wide analysis of aminoacyl-sulfamoyl-3-deazaadenosine analogues as inhibitors of aminoacyl-tRNA synthetases

Doi:10.1016/j.ejmech.2018.02.013
(2018)

Article Doi