Asymmetric trimethylsilylcyanation of benzaldehyde catalyzed by (salen)Ti(IV) complexes derived from (R)- and/or (S)-4-hydroxy-5-formyl[2.2]paracyclophane and diamines

DOI: 10.1016/S0957-4166(97)00406-0

Source and publish data:

Tetrahedron Asymmetry p. 3245 - 3250 (1997)

Update date:2022-08-16

Topics:

Authors:

Belokon', Yuri

Moscalenko, Margarita

Ikonnikov, Nicolai

Yashkina, Lidia

Antonov, Dmitri

Vorontsov, Evgeni

Rozenberg, Valeria

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Article abstract of DOI:10.1016/S0957-4166(97)00406-0

Benzaldehyde has been asymmetrically trimethylsilylcyanated, using chiral (salen)Ti(IV) catalysts 1a and 1b, 2a and 2b, 3a and 3b prepared in situ from titanium tetraisopropoxide and the Schiff's bases derived from (R)- or (S)-4-hydroxy-5-formyl[2.2]parac

Full text of DOI:10.1016/S0957-4166(97)00406-0

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Product name:Benzeneacetonitrile, a-[(trimethylsilyl)oxy]-, (R)-

Cas No:120443-82-5

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