Asymmetric trimethylsilylcyanation of benzaldehyde catalyzed by (salen)Ti(IV) complexes derived from (R)- and/or (S)-4-hydroxy-5-formyl[2.2]paracyclophane and diamines

DOI: 10.1016/S0957-4166(97)00406-0

Source and publish data:

Tetrahedron Asymmetry p. 3245 - 3250 (1997)

Update date:2022-08-16

Topics:

Authors:

Belokon', Yuri

Moscalenko, Margarita

Ikonnikov, Nicolai

Yashkina, Lidia

Antonov, Dmitri

Vorontsov, Evgeni

Rozenberg, Valeria

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0957-4166(97)00406-0

Benzaldehyde has been asymmetrically trimethylsilylcyanated, using chiral (salen)Ti(IV) catalysts 1a and 1b, 2a and 2b, 3a and 3b prepared in situ from titanium tetraisopropoxide and the Schiff's bases derived from (R)- or (S)-4-hydroxy-5-formyl[2.2]parac

Full text of DOI:10.1016/S0957-4166(97)00406-0

Products guided by the article

Product name:Benzeneacetonitrile, a-[(trimethylsilyl)oxy]-, (R)-

Cas No:120443-82-5

R&D Labs maybe for 120443-82-5

Changzhou BaoKang Pharmaceutical & Chemical Co., Ltd

Contact:(86) 519-88782201 88784080 88785278

Address:Henglin town, changzhou,Jiangsu
KangZhiYuan Pharmaceutical Company Limited

Contact:(Sabrina)86-20-85273232

Address:4th floor, building B, Dadi industry zone, Tangxia, Tianhe, Guangzhou, China
HaiNan Periwinkle Pharmaceutical Co.,Ltd.

website:http://www.cchpharm.com/en/index.html

Contact:020-82208978

Address:Gongye road,Wuzhishan city,HaiNan province
Rely Chemicals Ltd.

Contact:+86-518-81061113

Address:No. 8 Lingzhou Road, Lianyungang, Jiangsu, China
Shanghai Forever Biotech Co., Ltd.

Contact:+86-21-69734790

Address:Room 5017/5019、5022、5024 of Technology Innovation Centre, No.1155, Gongyuan East Rd, QingPu District, Shanghai China.

Relevant to this article

Synthesis and catalytic study of open metal site metal–organic frameworks of Cu₃(BTC)₂ microbelts in selective organic sulfide oxidation

Doi:10.1002/aoc.3528
(2016)
Synthesis, photophysical, electrochemical and single-crystal x-ray diffraction study of (Z)-2-phenyl-3-(5-(4-(thiophen-2-yl)benzo[c][1,2,5]thiadiazol-7-yl)thiophen-2-yl)acrylonitrile

Doi:10.1080/00397911.2016.1185125
(2016)
γ-Valerolactone as an alternative biomass-derived medium for the Sonogashira reaction

Doi:10.1039/c4gc01728e
(2015)
N-bromosuccinimide/cerium ammonium nitrate: An efficient reagent for stereo-controlled deamination of ketoaziridines

Doi:10.3184/174751914X14176157994656
(2014)
A cyanoallyl glucoside from Alliaria petiolata, as a feeding deterrent for larvae of Pieris napi oleracea

Doi:10.1021/np000534d
(2001)
N-Methylpiperidinium chlorochromate adsorbed on alumina: A new deoximation reagent

Doi:10.1007/s007060170038
(2001)

Article Doi