UNTERSUCHUNG DER EIGENSCHAFTEN EINES UNGEWOEHNLICHEN DISCHWEFELLIGANDEN: VERGLEICHENDE BETRACHTUNG DER CHEMIE VON (C5Me5)2Cr21-S2)(μ,η2-S2)(μ-S)> und (C5Me5)2Mo2(μ,η2-S2)(μ-S)2

DOI: 10.1016/S0022-328X(00)99182-4

Source and publish data:

Journal of Organometallic Chemistry p. 183 - 192 (1984)

Update date:2022-08-11

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Authors:

Brunner, Henri

Kauermann, Heike

Meier, Walter

Wachter, Joachim

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Article abstract of DOI:10.1016/S0022-328X(00)99182-4

The uncoordinated sulphur of the iso-μ(η¹-S₂) ligand in (C5Me5)2Cr2S5 is easily abstracted by PPh3 causing formation of (C5Me5)2Cr2S4, isoelectronic with (C5Me5)2Mo2(μ-S2)(μ-S)2.From the nature of the products <(C5Me5)2Cr2S5H>PF6, <(

Full text of DOI:10.1016/S0022-328X(00)99182-4

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