Preparation and trapping of 3-lithium-O-lithiophenoxide

DOI: 10.1016/S0040-4039(00)60341-6

Source and publish data:

Tetrahedron Letters p. 2043 - 2046 (1993)

Update date:2022-08-11

Topics:

Authors:

Selnick Selnick

Bourgeois

Butcher Butcher

Radzilowski

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Article abstract of DOI:10.1016/S0040-4039(00)60341-6

3-Bromophenol and 3-bromothiophenol are converted into the title compounds by proton abstraction followed by halogen-metal exchange with tert-butyllithium. The resulting dianions are then trapped on carbon with various electrophiles.

Full text of DOI:10.1016/S0040-4039(00)60341-6

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