Optically Active Transition-Metal Complexes. 102. Enantioselective Synthesis of 3-Oxabicyclooct-7-en-7-phenyl-6-on via Khand-Pauson Reaction

DOI: 10.1016/S0957-4166(00)82380-0

Source and publish data:

Tetrahedron Asymmetry p. 711 - 714 (1990)

Update date:2022-08-11

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Authors:

Brunner, Henri

Niedernhuber, Alwin

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Article abstract of DOI:10.1016/S0957-4166(00)82380-0

3-Oxabicyclo<3.3.0>oct-7-en-7-phenyl-6-on is obtained in the enantioselective Khand-Pauson reaction of (-)₅₄₆-Co2(CO)5(PhC2H)(GLYPHOS), GLYPHOS = (R)-(+)-2,3-O-isopropylidenglycerol-1-diphenylphosphane with 2,5-dihydrofuran.Complete resolution

Full text of DOI:10.1016/S0957-4166(00)82380-0

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