Journal of Organic Chemistry p. 5202 - 5204 (1989)
Update date:2022-08-11
Topics:
Knochel, Paul
Chou, Tso-Sheng
Chen, Huai Gu
Yeh, Ming Chang P.
Rozema, Michael J.
The rectivity of the new zinc and copper carbenoids PivOCH2Cu(CN)ZnI (4) and ICH2Cu*ZnI2 (5) toward various electrophiles has been investigated.Of special interest is the direct and highly stereoselective conversion of allylic bromides to the corresponding homoallylic iodides by using the reagent ICH2Cu*ZnI2
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