Nucleophilic Reactivity of Zinc and Copper Carbenoids. 2

DOI: 10.1021/jo00283a006

Source and publish data:

Journal of Organic Chemistry p. 5202 - 5204 (1989)

Update date:2022-08-11

Topics:

Authors:

Knochel, Paul

Chou, Tso-Sheng

Chen, Huai Gu

Yeh, Ming Chang P.

Rozema, Michael J.

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Article abstract of DOI:10.1021/jo00283a006

The rectivity of the new zinc and copper carbenoids PivOCH2Cu(CN)ZnI (4) and ICH2Cu*ZnI2 (5) toward various electrophiles has been investigated.Of special interest is the direct and highly stereoselective conversion of allylic bromides to the corresponding homoallylic iodides by using the reagent ICH2Cu*ZnI2

Full text of DOI:10.1021/jo00283a006

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