Nucleophilic Reactivity of Zinc and Copper Carbenoids. 2

DOI: 10.1021/jo00283a006

Source and publish data:

Journal of Organic Chemistry p. 5202 - 5204 (1989)

Update date:2022-08-11

Topics:

Authors:

Knochel, Paul

Chou, Tso-Sheng

Chen, Huai Gu

Yeh, Ming Chang P.

Rozema, Michael J.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00283a006

The rectivity of the new zinc and copper carbenoids PivOCH2Cu(CN)ZnI (4) and ICH2Cu*ZnI2 (5) toward various electrophiles has been investigated.Of special interest is the direct and highly stereoselective conversion of allylic bromides to the corresponding homoallylic iodides by using the reagent ICH2Cu*ZnI2

Full text of DOI:10.1021/jo00283a006

Products guided by the article

Product name:3-<(pivaloyloxy)methyl>cyclohexanone

Cas No:123290-33-5

R&D Labs maybe for 123290-33-5

taizhou creating bio-pharm co.,ltd.

Contact:+86- 576- 88827176

Address:715 room ,unit A.junyue Building,Jiaojiang,Taizhou,Zhejiang,China
Anhui Asahikasei Chemical Co., Ltd

Contact:86-551-4259770

Address:No. 88 Linquan Road Hefei Anhui China
Shanxi Sanwei Group Co.,Ltd

Contact:0086-357-6662688

Address:Zhaocheng town, Hongtong County, Linfen City, Shanxi Province
hangzhou verychem science and technology co.ltd

website:http://www.verypharm.com

Contact:+86-571-88162785; 88162786

Address:F1502, 753 Shenhua road, Hangzhou, China
Changzhou Ruiping Chemical Co., Ltd

website:http://www.wishchem.com

Contact:+86-519-82324280

Address:No.288-1 Huacheng Road, Jintan

Relevant to this article

Development of a Continuous Flow Synthesis of 2-Substituted Azetines and 3-Substituted Azetidines by Using a Common Synthetic Precursor

Doi:10.1021/acs.joc.1c01297
(2021)
Cyclopropane ring formation by an SmI₂ mediated cyclisation of ??-halo-?±,?2-unsaturated esters

Doi:10.1016/S0040-4039(99)01816-X
(1999)
The formation of a novel Pd/C-ethylenediamine complex catalyst: Chemoselective hydrogénation without deprotection of the o-benzyl and ZV-Cbz groups

Doi:10.1021/jo9814694
(1998)
Ring-opening reactions of cyclopropanes. Part 7.¹ Selenenylation and cyanoselenenylation of ethyl 2,2-dimethoxycyclopropanecarboxylates

Doi:10.1039/b109480g
(2002)
Benzoquinone Cocatalyst Contributions to DAF/Pd(OAc)₂-Catalyzed Aerobic Allylic Acetoxylation in the Absence and Presence of a Co(salophen) Cocatalyst

Doi:10.1021/acscatal.1c01074
(2021)
Synthesis, characterization and photophysical properties of polyfunctional phenylsilsesquioxanes: [o-RPhSiO_1.5]₈, [2,5-R ₂PhSiO_1.5]₈, and [R₃PhSiO _1.5]₈. compounds with the highest number of functional units/unit volume

Doi:10.1039/c1jm11701g
(2011)

Article Doi