
Journal of the Chemical Society. Chemical communications p. 202 - 203 (1987)
Update date:2022-08-16
Topics:
Moriarty, Robert M.
Prakash, Indra
Penmasta, Raju
Acetophenones, α-hydroxyacetophenones, deoxybenzoin, benzoin, and benzil are cleaved oxidatively with pentafluoroiodobenzene bis(-trifluoroacetate) in wet benzene at room temperature to give the corresponding benzoic acids; cyclohexanone and dimedone are cleaved to give the diacids adipic acid and 3,3-dimethylglutaric acid, respectively.
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