
Journal of the Chemical Society - Faraday Transactions p. 1037 - 1038 (1991)
Update date:2022-08-30
Topics:
Frost, Michael J.
Salh, Jatinder S.
Smith, Ian W. M.
A tunable diode laser has been used to observe transient absorptions on transitions in the ν3 infrared bands of CO2 when it is formed as a product of the flash-initiated reaction between OH and CO.The absence of any population in excited states with $v3 > 0 and the limited extent of excitation in the Fermi-linked $v1 and ν2 modes indicate that energy is released largely as repulsion following passage through a transition state in which the OCO atoms are close to their final structure in isolated CO2.
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