Homogeneous Catalysis of the Water Gas Shift Reaction with the Use of Group 6 Transition Metal Carbonyls: Cr(CO)6, Mo(CO)6, and W(CO)6

Article abstract of DOI:10.1021/ja00400a035

Measurements have been carried out to determine the rate of hydrogen production by the water gas shift reaction (CO + H2O -> CO2 + H2) operating at temperatures of 200 deg C and lower with hexacarbonyls of chromium, molybdenum, and tungsten serving as cat