Journal of the Chemical Society - Faraday Transactions p. 3241 - 3244 (1992)
Update date:2022-08-17
Topics:
Cherrak, Ahmed
Hubaut, Robert
Barbaux, Yolande
The oxidative coupling of methane has been studied over a pure samarium oxide catalyst by classical tests and surface potential measurements.This latter technique provides some interesting information on the nature of the oxygen species adsorbed over the catalytic surface and on the kinetic parameters of the reactions which take place on the solid.In our experimental conditions (PCH4/PO2 = 2) the negatively adsorbed oxygen species involved in the catalytic process is O- below 400 deg C and O2- at higher temperature.The reactivities of the hydrocarbons follow the order C2 >> methane, whatever the temperature.The activation energy obtained from classical tests (95 kJ mol-1) is very close to that obtained from surface-potential experiments.The results lead us to propose that an important part of the C2 yield limitation is due to the heterogeneous process.
View MoreContact:(1) 206-3550089
Address:5115 NE 8TH PL, Renton, WA 98059 USA
Hubei Sky Lake Chemical Co., Ltd.
Contact:+86-27-87385545
Address:Te-2, Xijiao Chemical Park, Yuekou Town, Tianmen, Hubei, China.
Shanghai Standard Biotech Co., Ltd.
Contact:+86-18502101150
Address:Room 103, Building 2nd, NO.720, Cailun Road , Pudong District, Shanghai, China
Shanghai He Yang International Trading Co., Ltd.
Contact:+86-21-52043598
Address:Room 816, Blag.5, No.58 Huachi Road
Changde Yungang Biotechnology Co., Ltd
website:http://www.cdyg.com
Contact:+86-736-7391178
Address:Qiaonan Industrial Park, Changde City, Hunan Province
Doi:10.1021/acs.orglett.1c02021
(2021)Doi:10.1021/cb500525p
(2014)Doi:10.1016/j.tetlet.2015.04.075
(2015)Doi:10.1002/ardp.200500154
(2005)Doi:10.1002/pola.26805
(2013)Doi:10.1016/j.catcom.2015.07.017
(2015)
