Journal of the Chemical Society. Chemical communications p. 911 - 912 (1993)
Update date:2022-08-16
Topics:
Agarwal, Sanjay K.
Spivey, James J.
Tevault, David E.
The effect of water vapour on the catalytic destruction of cyanogen chloride (CNCl) over a commercial Pt/α-alumina catalyst is to increase the overall conversion of CNCl, apparently by hydrolysis, providing a reaction path parallel to oxidation; the presence of water vapour also lowers the apparent activation energy for CNCl destruction, and the selectivity for CO formation is negligible in the presence of water vapour.
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