Synthesis and crystal structure of η3-phosphaallyl-molybdenum and -tungsten complexes

DOI: 10.1016/0022-328X(89)87119-0

Source and publish data:

Journal of Organometallic Chemistry p. 325 - 334 (1989)

Update date:2022-08-16

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Authors:

Goff, Catherine Hugel-Le

Mercier, Francois

Ricard, Louis

Mathey, Francois

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Article abstract of DOI:10.1016/0022-328X(89)87119-0

The reaction of the (phenyl)(vinyl)chlorophosphine (PW(CO)5 complex with 2 at 140 deg C affords, inter alia, the corresponding η³-phosphoallyl cpMo(CO)2 complex as a mixture of two isomers.In the major isomer the Mo(CO)2 group is san

Full text of DOI:10.1016/0022-328X(89)87119-0

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